TTU General Chemistry

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Chem 111 - Quiz 6A - Fall, 1996
Chapters VI, VII: Chemical Periodicity and Bonding

1. In predicting the electron configuration of the elements by the Aufbau Principle, to which sublevel is one adding electrons in traversing from element 39, Y, to element 48, Cd?

a) 4f
b) 5p
c) 4d
d) 5d

2. The number of valence electrons in the Group including nitrogen, phosphorus, and arsenic is:

a) 5
b) 4
c) 3
d) 7

3. Of the 3 elements fluorine, bromine, and calcium, which has the highest and which the lowest ionization energy?

a) Bromine has the highest and calcium has the lowest.
b) Calcium has the highest and fluorine has the lowest.
c) Fluorine has the highest and bromine has the lowest.
d) Fluorine has the highest and calcium has the lowest.

4. Rank the following five atomic species in order of increasing atomic radius (smallest to largest): Si, Na, K, F, O

a) K, Na, Si, O, F
b) F, O, Si, Na, K
c) O, F, Si, Na, K
d) O, F, Na, Si, K

5. The hydride ion has ____ electrons.

a) 2
b) 1
c) 0
d) 3

6. Which ionic species would you predict to be the largest? Na+, Mg2+, N3-, O2-

a) Mg2+
b) O2-
c) Na+
d) N3-

7. The Mg2+ ion is isoelectronic with which neutral atom?

a) Si
b) Na
c) Ne
d) Ar

8. Between which two species out of the following three elements is there the largest electronegativity difference? O, Se, Mg

a) Between Mg and Se, with Se being the highest EN.
b) Between O and Se, with O being the highest EN.
c) Between Mg and O, with Mg being the highest EN.
d) Between O and Mg, with O being the highest EN.

9. Identify the INCORRECT statement below:

a) Nonmetals generally have the higher electronegativities and tend to attract electrons to themselves in a chemical bond.
b) Elements with high ionization energies tend to have large atomic radii.
c) Elements with high electronegativities generally have large negative electron affinities.
d) The second ionization energy is always larger than the first ionization energy.

10. Which of the following is NOT true of the compound K2O?

a) It is named potassium peroxide.
b) It is a basic anhydride.
c) It is a metal oxide.
d) It forms potassium hydroxide when it reacts with water.

11. Which of the following processes is responsible for the yellowish-brown gas commonly found in the air over large metropolitan areas?

a) The electric spark in electric motors.
b) The combustion of coal with high sulfur content.
c) The combustion of materials containing nitrogen.
d) The combustion of natural gas.

12. Which Lewis Dot Formula below is INCORRECT?

13. What is the total number of available valence electrons in the Lewis dot structure of the ammonium ion, NH4+?

a) 8
b) 9
c) 10
d) 7

14. The Lewis dot formula for Br2 shows:

a) a single ionic bond
b) a double covalent bond
c) a triple covalent bond
d) a single covalent bond

15. Which is the correct Lewis dot structure of magnesium chloride?

16. Based on the Lewis electron dot structure of the diatomic molecule O2, what kind of bond exists between the oxygen atoms?

a) a triple covalent bond
b) a double covalent bond
c) a single covalent bond
d) a single ionic bond

17. Which is the correct Lewis structure of the SO32- ion?

18. In which species is there a violation of the octet rule?

a) N2
b) SF6
c) O2
d) CCl4

19. Which of the following statements about chemical periodicity is INCORRECT?

a) The chemical properties of elements are periodic functions of their atomic number.
b) Electronegativity decreases as you go from left to right across a period.
c) Atomic radii decrease as you go across a period.
d) Electron affinity becomes more negative as you go up a family or group of elements.

KEY (corrected as of 10/22/97)

1)c 2)a 3)d 4)b 5)a 6)d 7)c 8)d 9)b 10)a 11)c 12)b 13)a 14)d 15)a 16)b 17)d 18)b 19)b